column 7 of the hazardous materials table

With less than 10 percent formaldehyde, are not subject to this subchapter. The manufacturer must provide such information to a representative of the Department upon request. a. (i) Tests must be performed on each type and size of bottle, for each manufacturing location. Amdt. Organization and Purpose Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must use the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. The caps must not contain more than an average of twenty-five hundredths of a grain of explosive composition per cap; c. The caps must be packed inside packagings constructed of cardboard not less than 0.013-inch in thickness, metal not less than 0.008-inch in thickness, non-combustible plastic not less than 0.015-inch in thickness, or a composite blister package consisting of cardboard not less than 0.013-inch in thickness and non-combustible plastic not less than 0.005-inch in thickness that completely encloses the caps; d. The minimum dimensions of each side and each end of the cardboard packaging must be 1/8th inch in height or more; e. The number of caps inside each packaging must be limited so that not more than 10 grains of explosives composition may be packed into one cubic inch of space, and not more than 17.5 grains of the explosive composition of toy caps may be packed in any inner packaging; f. Inner packagings must be packed in outer packagings meeting PG II performance criteria; g. Toy caps may be packed with non-explosive or non-flammable articles provided the outer packagings are marked as prescribed in this paragraph; h. Toy paper caps of any kind must not be packed in the same packaging with fireworks; i. Except for transportation by aircraft, as an inner packaging of a combination packaging with a maximum net mass of 40 kg (88 pounds). In accordance with Special Provision 8 in 172.102, which is referenced in Column 7 of the Hazardous Materials Table (HMT; 172.101) for the entry "UN3082, Environmentally hazardous substance, liquid, n.o.s.," a hazardous substance that is not a hazardous waste may be shipped under the shipping description "Other regulated substances . or existing codification. The manufacturer must apply procedures to ensure that articles produced in series are made of good quality, conform to the design type and are able to meet the requirements in (a). A191 Notwithstanding the Division 6.1 subsidiary risk for this description, the toxic subsidiary risk label and the requirement to indicate the subsidiary risk on the shipping paper are not required for manufactured articles containing less than 5 kg (11 pounds) of mercury. 49 Mixtures of solids that are not subject to this subchapter and corrosive liquids may be transported under this entry without first applying the classification criteria of Class 8, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. A30 Ammonium permanganate is not authorized for transportation on aircraft. is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. However, sediments remaining in the tank that meet the definition for a hazardous material are subject to the applicable regulations of this subchapter. Quantities of not more than 500 g per package with not less than 10 percent water by mass may also be classed in Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). The purpose of this article is to explain the meaning of the coding system for the Special Provisions of column 7 in order to facilitate your review and understanding of them and how they may apply to your shipment of a hazardous material. While columns 8 and 7 of the Hazardous Materials Table are used to determine authorized packaging for most HazMat (more on that in a little bit), some methods of transportation, HazMat quantities, and specific operations rely on other methods. B10 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks, and DOT 57 portable tanks are not authorized. 357 A bulk packaging that emits hydrogen sulfide in sufficient concentration that vapors evolved from the crude oil can present an inhalation hazard must be marked as specified in 172.327 of this part. metal other than steel or aluminum (50N). The adsorption or absorption presents the following properties: (1) The pressure at a temperature of 20 C (68 F) in the receptacle is less than 0.6 bar (60 kPa); (2) The pressure at a temperature of 35 C (95 F) in the receptacle is less than 1 bar (100 kPa); (3) The pressure at a temperature of 85 C (185 F) in the receptacle is less than 12 bar (1200 kPa). 151 If this material meets the definition of a flammable liquid in 173.120 of this subchapter, a FLAMMABLE LIQUID label is also required and the basic description on the shipping paper must indicate the Class 3 subsidiary hazard. 127 Mixtures containing oxidizing and organic materials transported under this entry may not meet the definition and criteria of a Class 1 material. 342 Glass inner packagings (such as ampoules or capsules) intended only for use in sterilization devices, when containing less than 30 mL of ethylene oxide per inner packaging with not more than 300 mL per outer packaging, may be transported in accordance with 173.4a of this subchapter, irrespective of the restriction of 173.4a(b) and the indication of forbidden in columns (9A) and (9B) of the 172.101 table provided that: a. We recommend you directly contact the agency responsible for the content in question. 105 The word Agents may be used instead of Explosives when approved by the Associate Administrator. The receptacles must be constructed with glass double walls having the space between the walls vacuum insulated and each receptacle must be transported in an outer packaging with sufficient cushioning and absorbent materials to protect the receptacle from damage. e. When offered for transport in an ammonia dispenser, the receptacles shall be connected to the dispenser in such a way that the assembly is guaranteed to have the same strength as a single receptacle. N88 Any metal part of a UN pressure receptacle in contact with the contents may not contain more than 65% copper, with a tolerance of 1%. 372 This entry applies to asymmetric capacitors with an energy storage capacity greater than 0.3 Wh. The HMT provides the basic information necessary to ship a hazardous material safely. (iii) T50 When portable tank instruction T50 is indicated in Column (7) of the 172.101 Hazardous Materials Table, the applicable liquefied compressed gas and chemical under pressure descriptions are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section. 78 This entry may not be used to describe compressed air which contains more than 23.5 percent oxygen. Each reference in this column to a material which is a hazardous waste or a hazardous substance, and whose proper shipping name is preceded in Column 1 of the Table by the letter "A" or "W", is modified to include " 173.203" or " 173.213", as appropriate for liquids and solids, respectively, on those occasions when the . Special Provision Letter Codes Used in Hazmat Table, Column 7 Column 7 uses eight letter codes. Except when the liquids are fully absorbed in solid material contained in sealed bags, for single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. The packing group assignment and packaging must be approved by the Associate Administrator for Hazardous Materials Safety on the basis of the criteria in 173.21 of this subchapter and the package type used for the Series 6(c) test. (i) These provisions apply to the transportation of hazardous materials in IM and UN Specification portable tanks. This includes vehicles transported in a packaging. 349 Mixtures of hypochlorite with an ammonium salt are forbidden for transport. 65 The group of alkaline earth metals includes magnesium, calcium, strontium, and barium. N84 The maximum quantity per package is 500 g (1.1 lbs.). The present arrangement occurs in such a way that one QA molecule is hydrogen-bonded to four neighboring molecules: two different molecules in one column and other two molecules in another column. The chemical under pressure must be classed based on the hazard characteristics of the components in the propellant; the liquid; or the solid. As a 135 Internal combustion engines installed in a vehicle must be described using Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. Formaldehyde solutions not containing methanol and not meeting the Class 3 flammable liquid criteria must be described using a different proper shipping name. 367 For the purposes of documentation and package marking: a. A56 Radioactive material with a subsidiary hazard of Division 4.2, Packing Group I, must be transported in Type B packages when offered for transportation by aircraft. This training must be documented in training records required by 172.704(d). 9 Packaging for certain PCBs for disposal and storage is prescribed by EPA in 40 CFR 761.60 and 761.65. Hazardous materials shipped under this entry are excepted from the labeling requirements of this subchapter unless offered for transportation or transported by aircraft and are not subject to the placarding requirements of subpart F of this part. Additionally, each cylinder must be visually inspected in accordance with CGA pamphlet, CGA C-6 (incorporated by reference, see 171.7). 369 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN 2978. For a battery whose voltage (electrical potential) exceeds 9 volts -, (1) When contained in a device, the device must be packaged in a manner that prevents unintentional activation or must have an independent means of preventing unintentional activation (e.g., packaging restricts access to activation switch, switch caps or locks, recessed switches, trigger locks, temperature sensitive circuit breakers, etc. (h) Column 7: Special provisions. 141 A toxin obtained from a plant, animal, or bacterial source containing an infectious substance, or a toxin contained in an infectious substance, must be classed as Division 6.2, described as an infectious substance, and assigned to UN 2814 or UN 2900, as appropriate. B55 Water-tight, sift-proof, closed-top, metal-covered hopper cars, equipped with a venting arrangement (including flame arrestors) approved by the Associate Administrator are also authorized. The first label code represents the primary hazard of the material. B25 Packagings must be made from monel or nickel or monel-lined or nickel-lined steel. Different Types of Solder- All Common Classifications TP36 For material assigned this portable tank special provision, portable tanks used to transport such material may be equipped with fusible elements in the vapor space of the portable tank. W10 When offered for transportation by vessel, the use of Large Packagings (see 171.8 of this subchapter) is prohibited. Overview of Hazardous Material Transportation Regulations (b) Preparation for transport. If chemical stabilization becomes ineffective at lower temperatures within the anticipated duration of transport, temperature control is required and is forbidden by aircraft. 23 This material may be transported under the provisions of Division 4.1 only if it is so packed that the percentage of diluent will not fall below that stated in the shipping description at any time during transport. B44 All parts of valves and safety relief devices in contact with lading must be of a material which will not cause formation of acetylides. 1 CFR 1.1 Lead compounds that have a solubility of 5% or less in accordance with this special provision are not subject to the requirements of this subchapter that pertain to Marine Pollutants. Rigid plastics: 11H1, 11H2, 21H1 and 21H2, c. Composite with plastic inner receptacle: 11HZ1, 11HZ2, 21HZ1 and 21HZ2, e. Wooden: 11C, 11D and 11F (with inner liners). PDF 173.242 49 CFR Ch. I (10-1-04 Edition) - GovInfo They must be classified in accordance with the procedure as set out in the Manual of Tests and Criteria, part III, section 39 (IBR, see 171.7 of this subchapter). Others such as copper and silver are available in trace amounts. b. Gases of Division 2.3 and gases with a subsidiary risk of 5.1 must not be used as a propellant in a chemical under pressure. 173 For adhesives, printing inks, printing ink-related materials, paints, paint-related materials, and resin solutions which are assigned to UN3082, and do not meet the definition of another hazard class, metal or plastic packaging for substances of packing groups II and III in quantities of 5 L (1.3 gallons) or less per packaging are not required to meet the UN performance package testing when transported: a. Pressing enter in the search box For example, nickel-metal hydride batteries transported by vessel in certain quantities are covered by another entry (see Batteries, nickel-metal hydride, UN3496). Furthermore, lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must be described using the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. (7) Special Provisions (172.102) IB8, IP2, IP4 For transportation by aircraft, articles, machinery, or apparatus, may not contain any material forbidden for transportation by passenger or cargo aircraft. N76 For materials of not more than 25 percent active ingredient by weight, packages consisting of inner metal packagings not greater than 250 mL (8 ounces) capacity each, packed in strong outer packagings together with sufficient absorbent material to completely absorb the liquid contents are authorized and need not conform to the requirements of part 178 of this subchapter. The consignor shall be in possession of a copy of each applicable certificate when packages include fissile material excepted by competent authority approval. B28 Packagings must be made of stainless steel. N43 Metal drums are permitted as single packagings only if constructed of nickel or monel. W9 When offered for transportation by water, the following Specification packagings are not authorized unless approved by the Associate Administrator: woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings. Lighter refills offered for transportation under this entry may not exceed 4 fluid ounces capacity (7.22 cubic inches) or contain more than 65 grams of fuel. Dry batteries not specifically covered by another entry in the 172.101 Table are covered by this entry (i.e., Batteries, dry, sealed, n.o.s.) Title 49 was last amended 2/03/2023. N83 This material may not be transported in quantities of more than 11.5 kg (25.4 lbs) per package. The coal tar pitch compound must be in a solid mass during transportation. A 25 mm (1 inch) woven lining of asbestos or other approved material must be placed between the bolster slabbing and the bottom of the tank. A3 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with absorbent material in tightly closed rigid and leakproof receptacles before packing in outer packagings. A series of notes is used throughout TABLE 1 and TABLE 2 to provide additional information concerning certain hazardous substances. Choosing an item from Ch 6.0b Flashcards | Quizlet c. Primary receptacles may also be further packed in specification bulk outer packagings. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. 238 Neutron radiation detectors: Neutron radiation detectors containing non-pressurized boron trifluoride gas in excess of 1 gram (0.035 ounces) and radiation detection systems containing such neutron radiation detectors as components may be transported by highway, rail, vessel, or cargo aircraft in accordance with the following: a. will also bring you to search results. Only Specifications MC 304, MC 307 or DOT 407 cargo tank motor vehicles are authorized for transportation by vessel. However, button cell batteries installed in equipment (including circuit boards) need not be considered; and, c. The shipping paper must indicate UN 3091 Lithium metal batteries packed with equipment or UN 3481 Lithium ion batteries packed with equipment, as appropriate. N40 This material is not authorized in the following packagings: a. These provisions apply only to transportation by water: W1 This substance in a non friable prill or granule form is not subject to the requirements of this subchapter when tested in accordance with the UN Manual of Test and Criteria (IBR, see 171.7 of this subchapter) and is found to not meet the definition or criteria for inclusion in Division 5.1. (1) Numeric provisions. B82 Cargo tanks and portable tanks are not authorized. B131 When transported by highway, rail, or cargo vessel, waste Paint and Paint related material (UN1263; PG II and PG III), when in plastic or metal inner packagings of not more than 26.5 L (7 gallons), are excepted from the marking requirements in 172.301(a) and (c) and the labeling requirements in 172.400(a), when further packed in the following specification and non-specification bulk outer packagings and under the following conditions: a. Essentially, such SSolder complies with RoHS (Restriction of Hazardous Substances) regulations. (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request. 21 This material must be stabilized by appropriate means (e.g., addition of chemical inhibitor, purging to remove oxygen) to prevent dangerous polymerization (see 173.21(f) of this subchapter). Learn more about the eCFR, its status, and the editorial process. They must be classified in accordance with the procedure as set out in the Manual of Tests and Criteria, part III, section 39 (IBR, see 171.7 of this subchapter). The eCFR is displayed with paragraphs split and indented to follow 166 When transported in non-friable tablet form, calcium hypochlorite, dry, may be transported as a Packing Group III material. Insulation must be at least 100 mm (3.9 inches) except that the insulation thickness may be reduced to 51 mm (2 inches) over the exterior heater coils. The Associate Administrator may except from the requirements of this subchapter articles, machinery, and apparatus provided: a. For transportation by passenger-carrying aircraft, the net mass of lighter refills may not exceed 1 kg per package, and, for cargo-only aircraft, the net mass of lighter refills may not exceed 15 kg per package. B136 Non-specification closed bulk bins are authorized. The requirements of 172.203(m) and 172.505 of this subchapter do not apply. 198 Nitrocellulose solutions containing not more than 20% nitrocellulose may be transported as paint, perfumery products, or printing ink, as applicable, provided the nitrocellulose contains no more 12.6% nitrogen (by dry mass). Insulating materials may not promote corrosion to steel when wet. What is Column 7 of the hazardous materials Table? Interpretation Response | PHMSA - Pipeline and Hazardous Materials The guns are packaged in accordance with Packing Method US 1 as specified in 173.62 of this subchapter. If the air bag inflator unit satisfactorily passes the series 6(c) test, it is not necessary to repeat the test on the air bag module. c. Self-propelled vehicles or equipment that also contain an internal combustion engine must be described using the entries Engine, internal combustion, flammable gas powered or Engine, internal combustion, flammable liquid powered or Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. ); and. It is shown that it does not pose a significant risk in transportation; b. formatting. In addition to meeting the conditions in this provision, transport on cargo aircraft only may be authorized with prior approval of the Associate Administrator. The Packing Group assigned will be II or III, according to the classification criteria for either Class 3 or Division 4.1, as appropriate, applied to the base material. subject to the Hazardous Materials Regulations must comply with all applicable requirements of Subpart F [172.500]. 381 For railroad flagging kits, see 173.184 (c) of this subchapter. N12 Plastic packagings are not authorized. The toy plastic or paper caps must be in the form of sheets, strips, rolls, or individual caps; b. These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. Transport vehicles must be vented to prevent accumulation of vapors at a poisonous or flammable concentration. Note that batteries utilizing different chemistries (i.e., those battery chemistries specifically covered by another entry in the 172.101 Table) as well as dry batteries with a marked rating greater than 9-volt may not be combined with used or spent batteries in the same package. Column 1 uses six symbols to identify hazardous materials with special shipping conditions such as restrictions for air, domestic, international, or water vessel transport. A copy of the approval shall accompany the shipping papers. What is Column 7 of the hazardous materials Table? The total weight of the explosive contents of the shaped charges assembled in the guns does not exceed 90.5 kg (200 pounds) per vehicle; and. Except for transportation by aircraft, in palletized loads, a pallet box or unit load device (e.g. 22 If the hazardous material is in dispersion in organic liquid, the organic liquid must have a flash point above 50 C (122 F). (v) The box must be constructed from high-density polyethylene in the density range 0.950-0.962, and be capable of holding liquid when in the upright position. It must be demonstrated that the article relieves its pressure by means of a fire degradable seal or other pressure relief device, in such a way that the pressure receptacle will not fragment and that the article or fragments of the article do not rocket more than 10 meters; and. Other inorganic nitrate salts may replace part of the ammonium nitrate. b. Packagings equivalent to DOT 406 cargo tanks are excepted from 178.345-7(d)(5), circumferential reinforcements; 178.345-10, pressure relief; 178.345-11, outlets; 178.345-14, marking, and 178.345-15, certification. A copy of the approval must accompany each shipment. learn more about the process here. (2) A codes. B134 For Large Packagings offered for transport by vessel, flexible or fibre inner packagings shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. How to Read the Hazardous Materials Table Packages containing mixtures with not less than 90% by mass, of phlegmatizer need not bear a POISON subsidiary risk label. 54 Maneb or maneb preparations not meeting the definition of Division 4.3 or any other hazard class are not subject to the requirements of this subchapter when transported by motor vehicle, rail car, or aircraft. The following tables list, and set forth the requirements of, the special provisions referred to in column 7 of the 172.101 table. Lading in unlined tanks must be inhibited so that the corrosive effect on steel is not greater than that of hydrofluoric acid of 65 percent concentration. 379 When offered for transport by highway, rail, or cargo vessel, anhydrous ammonia adsorbed or absorbed on a solid contained in ammonia dispensing systems or receptacles intended to form part of such systems is not subject to the requirements of this subchapter if the following conditions in this provision are met. Unfortunately, the amendments to the table entries for various hazardous materials introduced new unintended errors that PHMSA is correcting in this notice. 106 The recognized name of the particular explosive may be specified in addition to the type. In this case, some parts of the vehicle may be detached from its frame to fit into the packaging. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. However, the hazard label corresponding to the hazard class or division may be substituted for the marking. (contains magnesium, magnesium nitrides) in PG II or III may be packaged in sift-proof bulk packagings that prevent liquid from reaching the hazardous material with sufficient venting to preclude dangerous accumulation of flammable, corrosive or toxic gaseous emissions such as methane, hydrogen and ammonia. 340 This entry applies only to the vessel transportation of nickel-metal hydride batteries as cargo. meet the venting requirements in 173.24(g) or (2.) Each radiation detector must meet the following conditions: (1) The pressure in each neutron radiation detector must not exceed 105 kPa absolute at 20 C (68 F); (2) The amount of gas must not exceed 13 grams (0.45 ounces) per detector; and, (3) Each neutron radiation detector must be of welded metal construction with brazed metal to ceramic feed through assemblies. 353 Ammonium permanganate, ammonium permanganate aqueous solutions, and mixtures of a permanganate with an ammonium salt are forbidden for transport. c. The cylinders are collected and transported by a private or a contract carrier for reconditioning, reuse or disposal. c. Every installed inflation cylinder, as associated equipment of the life-saving appliance, must be packed within the protective packaging of the life raft and the life raft itself must otherwise be in compliance with 173.219. d. The serial number for each cylinder must be recorded as part of the life-saving appliance service record by the U.S. Coast Guard-approved servicing facility. 347 Effective July 1, 2011, for transportation by aircraft, this entry may only be used if the results of Test series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. 145 This entry applies to formulations that neither detonate in the cavitated state nor deflagrate in laboratory testing, show no effect when heated under confinement, exhibit no explosive power, and are thermally stable (self-accelerating decomposition temperature (SADT) at 60 C (140 F) or higher for a 50 kg (110.2 lbs.)

Is Judge Emmet Sullivan Married, Articles C

PAGE TOP